Jim, did the floor under the toilet look as though it had ever leaked?
How does it smell dry?
How does it smell if you spray it with distilled water?
I'm thinking of what Jon said, and about what happened to Warren.
If the area around the toilet is dry though before the test and after the test I do not think saturated wood is the villain. If it were I think there would be an odor all the time even when the toilet were not in use. I don't think you said there was an odor all the time.
You could test the vent by ingesting an "controlled odor" into the toilet that would not be confused with the usual toilet odor (such as citronella, bleach or vinegar etc) and see if you still thought the vent were working as properly as you believe.
You could fit a vacuum cleaner and pull a suction on the vent and test the toilet the regular way and see if there were still an odor. Make a very loose, imperfect connection to that vacuum, or you may get an effect you don't need
You also neglected to say if this condition just started, or that you have had it all along.
JIM